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doi: 10.1016/j.jogc.2022.10.012 [DOI] [PubMed] [Google Scholar] 166.Syed YY

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Although spontaneous thermal homolysis of S-nitrosothiols has been discussed in the literature, theoretical and experimental analysis has indicated that activation energies are too high for spontaneous S-N bond homolysis to be a biologically meaningful reaction (reported half-lives are years to hours at 100°C) [22]